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Lithiumbromit
ββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββ
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Lithiumbromit ist eine chemische Verbindung aus der Gruppe der Bromite.
Contents
β’ Eigenschaften
β’ Einzelnachweise
ββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββββ
Gewinnung und Darstellung
Lithiumbromit kann durch Reaktion von Lithiumbromat mit Lithiumbromid bei 190 bis 220 Β°C gewonnen werden.cite-ref-kurt-h-stern-1-2[1]
2 LiBrO 3 + LiBr βΆ βΆ 3 LiBrO 2 {\displaystyle {\ce {2 LiBrO3 + LiBr -> 3 LiBrO2}}}
Die Verbindung kann auch durch Reaktion von Bromiger SΓ€ure mit Lithiumhydroxid dargestellt werden.cite-ref-yu-i-ostroushko-3-0[3]
LiOH + HBrO 2 βΆ βΆ LiBrO 2 + H 2 O {\displaystyle {\ce {LiOH + HBrO2 -> LiBrO2 + H2O}}}
Eigenschaften
Lithiumbromit ist ein sehr hygroskopischer Feststoff, der sich bei 225 Β°C unter Schmelzen zersetzt.cite-ref-kurt-h-stern-1-3[1]
LiBrO 2 βΆ βΆ LiBr + O 2 {\displaystyle {\ce {LiBrO2 -> LiBr + O2}}}
Einzelnachweise
cite-note-kurt-h-stern-11. Kurt H. Stern: High Temperature Properties and Thermal Decomposition of Inorganic Salts with Oxyanions. CRC Press, 2000, ISBN 1-4200-4234-3, S. 226 (eingeschrΓ€nkte Vorschau in der Google-Buchsuche).
cite-note-nv-21. Dieser Stoff wurde in Bezug auf seine GefΓ€hrlichkeit entweder noch nicht eingestuft oder eine verlΓ€ssliche und zitierfΓ€hige Quelle hierzu wurde noch nicht gefunden.
cite-note-yu-i-ostroushko-33. β Yu. I. Ostroushko: Lithium, Its Chemistry and Technology. U.S. Atomic Energy Commission, Division of Technical Information, 1962, S. 84 (eingeschrΓ€nkte Vorschau in der Google-Buchsuche).